Multiscale and hierarchical reaction mechanism in a lithium-ion battery
نویسندگان
چکیده
The key to improving the performance of lithium-ion batteries is precisely elucidate temporal and spatial hierarchical structure battery. Lithium-ion consist cathodes anodes a separator containing an electrolyte. are made composite material consisting active material, conductive binder form complex three-dimensional structure. reaction proceeds as lithium ions repeatedly inserted into removed from material. Therefore, lattice restructured due ion diffusion, which results in phase change. At material–electrolyte interface, insertion de-insertion proceed with charge transfer reaction. charge–discharge battery nonequilibrium state interplay multiple phenomena. Analysis after disassembling battery, performed conventional research, does not provide accurate understanding dominant factors rate degradation mechanism, some cases. This review introduces research on batteries, focusing operando measurements taken during reactions. Chapter 1 provides overview mechanism batteries. 2 measurement technique, useful for analysis. 3 describes at electrode–electrolyte field, 4 discusses structural change caused by two-phase 5 study unique heterogeneity electrode, enables practical energy storage. Understanding will information design next-generation
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ژورنال
عنوان ژورنال: Chemical physics reviews
سال: 2022
ISSN: ['2688-4070']
DOI: https://doi.org/10.1063/5.0062329